Notizen. Darstellung und einige Reaktionen von cis, cis‐2,4‐Di‐tert‐butylmuconsäureanhydrid

G. Speier, Zoltán Tyeklár

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Abstract

Preparation and Some Reactions of cis,cis‐2,4‐Di‐tert‐butylmuconic Anhydride cis,cis‐2,4‐Di‐tert‐butylmuconic anhydride (1) was prepared by the Baeyer‐Villiger reaction from 3,5‐di‐tert‐butyl‐o‐benzoquinone with monoperphthalic acid in 76% yield. It is relatively stable against water and reacts with aqueous sodium hydroxide to give 2,4‐di‐tert‐butyl‐2,5‐dihydro‐5‐oxo‐2‐furanacetic acid (2), with methanol to form the corresponding ester 3 and with dry ammonia to yield the corresponding amide 4. All compounds were characterized spectroscopically.

Original languageGerman
Pages (from-to)389-391
Number of pages3
JournalChemische Berichte
Volume112
Issue number1
DOIs
Publication statusPublished - 1979

ASJC Scopus subject areas

  • Chemistry(all)
  • Inorganic Chemistry

Cite this

Notizen. Darstellung und einige Reaktionen von cis, cis‐2,4‐Di‐tert‐butylmuconsäureanhydrid. / Speier, G.; Tyeklár, Zoltán.

In: Chemische Berichte, Vol. 112, No. 1, 1979, p. 389-391.

Research output: Contribution to journalArticle

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