Non-reversible solvatochromism in N-methyl-2-pyrrolidone/toluene mixed solutions of fullerene C60

O. A. Kyzyma, T. Kyrey, M. V. Avdeev, M. V. Korobov, L. A. Bulavin, V. Aksenov

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Non-reversible changes in the UV-Vis spectra (solvatochromism) of C 60 fullerene in the binary solvent N-methyl-2-pyrrolidone/toluene are observed when varying the mixture composition. The solvatochromism strongly depends on the order of the mixture preparation. We attribute the effect to a great difference in the polarity of the liquid components, which determines different solvent-solute interaction with respect to the formation of charge-transfer complexes and, thus, provides conditions for selective solvation. The effect is also dependent on the temporal changes in the complexes C60-N-methyl-2-pyrrolidone and C60 cluster formation.

Original languageEnglish
Pages (from-to)178-181
Number of pages4
JournalChemical Physics Letters
Volume556
DOIs
Publication statusPublished - Jan 29 2013

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Toluene
fullerenes
toluene
Solvation
solvation
Charge transfer
polarity
solutes
charge transfer
preparation
Liquids
liquids
Chemical analysis
interactions
fullerene C60
N-methylpyrrolidone

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Cite this

Non-reversible solvatochromism in N-methyl-2-pyrrolidone/toluene mixed solutions of fullerene C60. / Kyzyma, O. A.; Kyrey, T.; Avdeev, M. V.; Korobov, M. V.; Bulavin, L. A.; Aksenov, V.

In: Chemical Physics Letters, Vol. 556, 29.01.2013, p. 178-181.

Research output: Contribution to journalArticle

Kyzyma, O. A. ; Kyrey, T. ; Avdeev, M. V. ; Korobov, M. V. ; Bulavin, L. A. ; Aksenov, V. / Non-reversible solvatochromism in N-methyl-2-pyrrolidone/toluene mixed solutions of fullerene C60. In: Chemical Physics Letters. 2013 ; Vol. 556. pp. 178-181.
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