[N,N′-Bis(2,4-dimethylbenzene)-2,3-dimethyl-1,4-diazabuta-1,3-diene] -fac-tricarbonyl(trifluoroacetato)rhenium(I)

Reza Kia, Valiollah Mirkhani, Andrea Deák, Alajos Kálmán

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

In the title compound, [Re(CF3COO)(C20H 24N2)(CO)3], the Re atom has a distorted octahedral configuration. The 1,4-diazabutadiene part of the donor ligand and two carbonyl groups occupy the equatorial plane of the complex, with the third carbonyl ligand and the trifluoroacetate group in the axial positions. The equatorial diimine ligand is bound to the Re center in an N,N′-bidentate chelating fashion, leading to a five-membered ReN2C2 chelate ring with an N - Re - N bite angle of 73.4 (2)°.

Original languageEnglish
Pages (from-to)m566-m567
JournalActa Crystallographica Section E: Structure Reports Online
Volume61
Issue number3
DOIs
Publication statusPublished - Mar 1 2005

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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