NMR geometry and interaction parameters of methylisocyanide in various liquid-crystalline environments

Y. Hiltunen, J. Jokisaari, J. Lounila, A. Pulkkinen, G. Dombi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The NMR rα geometry of methylisocyanide has been studied in two liquid-crystal solvents and their mixtures by applying both the conventional technique, which takes into consideration only the harmonic vibrational effects on the dipolar couplings, and a method which also allows for orientation-dependent molecular deformations induced by the anisotropic environment. The latter analysis gives as a by-product the interaction parameters, ΔA, which describe the anisotropic forces acting on the three different bonds of methylisocyanide dissolved in liquid-crystalline phases.

Original languageEnglish
Pages (from-to)353-357
Number of pages5
JournalChemical Physics Letters
Volume148
Issue number4
DOIs
Publication statusPublished - Jul 15 1988

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Liquid Crystals
Byproducts
liquid crystals
Nuclear magnetic resonance
Crystalline materials
harmonics
nuclear magnetic resonance
Geometry
Liquids
liquids
geometry
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

NMR geometry and interaction parameters of methylisocyanide in various liquid-crystalline environments. / Hiltunen, Y.; Jokisaari, J.; Lounila, J.; Pulkkinen, A.; Dombi, G.

In: Chemical Physics Letters, Vol. 148, No. 4, 15.07.1988, p. 353-357.

Research output: Contribution to journalArticle

Hiltunen, Y. ; Jokisaari, J. ; Lounila, J. ; Pulkkinen, A. ; Dombi, G. / NMR geometry and interaction parameters of methylisocyanide in various liquid-crystalline environments. In: Chemical Physics Letters. 1988 ; Vol. 148, No. 4. pp. 353-357.
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