Nitrogen bridgehead compounds. Part 60. Unusual amination with sodium azide.

I. Bitter, Gábor Tóth, A. Szöllösy, I. Hermecz, Zoltán Mészáros

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

9-Bromo-6,7,8,9-tetrahydro-4H-pyrido [1,2-a]pyrimidin-4-ones react with sodium azide to afford 9-amino-6,7-dihydroanalogues. A mechanism involving a tricyclic tetrazine intermediate formed by neighbouring-group participation is suggested.

Original languageEnglish
Pages (from-to)3621-3622
Number of pages2
JournalTetrahedron Letters
Volume26
Issue number30
DOIs
Publication statusPublished - 1985

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Nitrogen Compounds
Amination
Sodium Azide

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Nitrogen bridgehead compounds. Part 60. Unusual amination with sodium azide. / Bitter, I.; Tóth, Gábor; Szöllösy, A.; Hermecz, I.; Mészáros, Zoltán.

In: Tetrahedron Letters, Vol. 26, No. 30, 1985, p. 3621-3622.

Research output: Contribution to journalArticle

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abstract = "9-Bromo-6,7,8,9-tetrahydro-4H-pyrido [1,2-a]pyrimidin-4-ones react with sodium azide to afford 9-amino-6,7-dihydroanalogues. A mechanism involving a tricyclic tetrazine intermediate formed by neighbouring-group participation is suggested.",
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AU - Bitter, I.

AU - Tóth, Gábor

AU - Szöllösy, A.

AU - Hermecz, I.

AU - Mészáros, Zoltán

PY - 1985

Y1 - 1985

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AB - 9-Bromo-6,7,8,9-tetrahydro-4H-pyrido [1,2-a]pyrimidin-4-ones react with sodium azide to afford 9-amino-6,7-dihydroanalogues. A mechanism involving a tricyclic tetrazine intermediate formed by neighbouring-group participation is suggested.

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