Nitrogen- and oxygen-bridged bidentate phosphaalkene ligands

Wolf Walther Du Mont, Roxana Bîrzoi, Delia Bugnariu, Constantin G. Daniliuc, Christine Goers, Rafael Guerrero Gimeno, Thorsten Gust, Daniela Lungu, Antje Riecke, Rainer Bartsch, Laszlo Nyulászi, Zoltan Benkõ, Laszlo Könczöl

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4 Citations (Scopus)

Abstract

An overview is given on synthesis and structures of new bidentate phosphaalkene ligands [(RMe2Si)2CP]2E (E = O, NR, N-) and (RMe2Si)2CPN(R)PR2. Exceptional properties of these ligands, extending beyond predictable properties of phosphaalkenes are: (i) the NSi bond cleavage of [(iPrMe2Si) 2CP]2NSiMe3 with AuI and Rh I chloro complexes under mild conditions leading to binuclear complexes of the 6π-delocalised imidobisphosphaalkene anion [(iPrMe 2Si)2CP]2N-, and (ii) the chlorotropic formation of molecular 1:2 PdII and PtII metallochloroylid complexes with novel ylid-type ligands [(RMe 2Si)2CP(Cl)N(R)PR2]-, and the transformation of a P-platina-P-chloroylid complex into a C-platina phosphaalkene by intramolecular chlorosilane elimination. Properties of the heavier congeners [(RMe2Si)2CP]2E (E = S, Se, Te, PR, P-, As-) and (RMe2Si) 2CPEPR2 (E = S, Se, Te) are also described.

Original languageEnglish
Pages (from-to)1111-1126
Number of pages16
JournalComptes Rendus Chimie
Volume13
Issue number8-9
DOIs
Publication statusPublished - Jan 1 2010

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Keywords

  • Bidentate phosphaalkenes
  • Gold
  • PNP ylid complexes
  • Palladium
  • Phosphaalkene complexes
  • Platinum
  • Rhodium

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Du Mont, W. W., Bîrzoi, R., Bugnariu, D., Daniliuc, C. G., Goers, C., Gimeno, R. G., Gust, T., Lungu, D., Riecke, A., Bartsch, R., Nyulászi, L., Benkõ, Z., & Könczöl, L. (2010). Nitrogen- and oxygen-bridged bidentate phosphaalkene ligands. Comptes Rendus Chimie, 13(8-9), 1111-1126. https://doi.org/10.1016/j.crci.2010.06.012