New types of telechelic polyisobutylenes, 1 synthesis and characterization of the bis(α,β-D-glucopyranosyl) polyisobutylene

Miklós Nagy, László Orosz, S. Kéki, G. Deák, P. Herczegh, M. Zsuga

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A new, simple, and effective synthetic method for the preparation of glucose-terminated polyisobutylenes starting from the corresponding hydroxyl-terminated polymers is reported. Detailed NMR and matrix-assisted laser desorption/ionization mass spectrometric (MALDI-TOF MS) investigations showed the exclusive presence of bis(glucopyranosyl) polyisobutylene. Dynamic light scattering (DLS) investigations of this polymer in solution in both tetrahydrofuran and water showed that microphase separation takes place by the formation of micelles and/or vesicles.

Original languageEnglish
Pages (from-to)1073-1077
Number of pages5
JournalMacromolecular Rapid Communications
Volume25
Issue number11
DOIs
Publication statusPublished - Jun 7 2004

Fingerprint

Polymers
Microphase separation
Micelles
Dynamic light scattering
Hydroxyl Radical
Ionization
Glucose
Desorption
Nuclear magnetic resonance
Water
Lasers
polyisobutylene
tetrahydrofuran

Keywords

  • Aggregates
  • Bis(glucopyranosyl) PIB
  • Light scattering
  • MALDI
  • NMR

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

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abstract = "A new, simple, and effective synthetic method for the preparation of glucose-terminated polyisobutylenes starting from the corresponding hydroxyl-terminated polymers is reported. Detailed NMR and matrix-assisted laser desorption/ionization mass spectrometric (MALDI-TOF MS) investigations showed the exclusive presence of bis(glucopyranosyl) polyisobutylene. Dynamic light scattering (DLS) investigations of this polymer in solution in both tetrahydrofuran and water showed that microphase separation takes place by the formation of micelles and/or vesicles.",
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T1 - New types of telechelic polyisobutylenes, 1 synthesis and characterization of the bis(α,β-D-glucopyranosyl) polyisobutylene

AU - Nagy, Miklós

AU - Orosz, László

AU - Kéki, S.

AU - Deák, G.

AU - Herczegh, P.

AU - Zsuga, M.

PY - 2004/6/7

Y1 - 2004/6/7

N2 - A new, simple, and effective synthetic method for the preparation of glucose-terminated polyisobutylenes starting from the corresponding hydroxyl-terminated polymers is reported. Detailed NMR and matrix-assisted laser desorption/ionization mass spectrometric (MALDI-TOF MS) investigations showed the exclusive presence of bis(glucopyranosyl) polyisobutylene. Dynamic light scattering (DLS) investigations of this polymer in solution in both tetrahydrofuran and water showed that microphase separation takes place by the formation of micelles and/or vesicles.

AB - A new, simple, and effective synthetic method for the preparation of glucose-terminated polyisobutylenes starting from the corresponding hydroxyl-terminated polymers is reported. Detailed NMR and matrix-assisted laser desorption/ionization mass spectrometric (MALDI-TOF MS) investigations showed the exclusive presence of bis(glucopyranosyl) polyisobutylene. Dynamic light scattering (DLS) investigations of this polymer in solution in both tetrahydrofuran and water showed that microphase separation takes place by the formation of micelles and/or vesicles.

KW - Aggregates

KW - Bis(glucopyranosyl) PIB

KW - Light scattering

KW - MALDI

KW - NMR

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