New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand

Irina L. Odinets, Tamás Körtvélyesi, Réka Herbay, Péter Bagi, György Keglevich

Research output: Contribution to journalArticle

Abstract

Reaction between the title bidental P-ligand (obtained from 4-chloro-5-methyl-1-phenyl-3-diphenylphosphoryl-l,2,3,6-tetrahydrophosphinine oxide by double deoxygenation using trichlorosilane or phenylsilane) and two equivalents of (Me5C5)RhCl2 led to the corresponding bis-RhIII complex whose structure was evaluated by ab initio and DFT calculations. Attempts to achieve selective complexation of either the ring or exocyclic P-function were unsuccessful.

Original languageEnglish
Pages (from-to)573-574
Number of pages2
JournalMendeleev Communications
Volume29
Issue number5
DOIs
Publication statusPublished - Sep 1 2019

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Rhodium
Complexation
Discrete Fourier transforms
Oxides
Ligands
trichlorosilane

ASJC Scopus subject areas

  • Chemistry(all)

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New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand. / Odinets, Irina L.; Körtvélyesi, Tamás; Herbay, Réka; Bagi, Péter; Keglevich, György.

In: Mendeleev Communications, Vol. 29, No. 5, 01.09.2019, p. 573-574.

Research output: Contribution to journalArticle

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AU - Bagi, Péter

AU - Keglevich, György

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