New bis-rhodium complex with a bidentate 3-phosphino-1,2,3,6-tetrahydrophosphinine P-ligand

Irina L. Odinets, Tamás Körtvélyesi, Réka Herbay, Péter Bagi, György Keglevich

Research output: Contribution to journalArticle

Abstract

Reaction between the title bidental P-ligand (obtained from 4-chloro-5-methyl-1-phenyl-3-diphenylphosphoryl-l,2,3,6-tetrahydrophosphinine oxide by double deoxygenation using trichlorosilane or phenylsilane) and two equivalents of (Me5C5)RhCl2 led to the corresponding bis-RhIII complex whose structure was evaluated by ab initio and DFT calculations. Attempts to achieve selective complexation of either the ring or exocyclic P-function were unsuccessful.

Original languageEnglish
Pages (from-to)573-574
Number of pages2
JournalMendeleev Communications
Volume29
Issue number5
DOIs
Publication statusPublished - Sep 1 2019

ASJC Scopus subject areas

  • Chemistry(all)

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