New application of an anchored Ru(II)-N-heterocyclic carbene complex

A. Zsigmond, Sushen Undrala, F. Notheisz, Gábor Papp, Ferenc Joó

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A new, heterogenized Ru(II)-N-heterocyclic carbene complex was prepared via the method developed by Augustine. The anchored catalyst was characterized by spectros-copic methods and was applied in the hydrogenation of different olefins, aldehydes and ketones. The hydrogenations were performed both in alcohol and in aqueous media on homogeneous and heterogenized complexes. The immobilized complex had a reasonable activity in both conditions and at the same time it was possible to filter out from the reaction mixture and to recycle in several subsequent runs.

Original languageEnglish
Pages (from-to)163-168
Number of pages6
JournalCatalysis Letters
Volume115
Issue number3-4
DOIs
Publication statusPublished - Jun 2007

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carbenes
Hydrogenation
hydrogenation
Alkenes
Ketones
Aldehydes
aldehydes
ketones
alkenes
Olefins
alcohols
Alcohols
filters
catalysts
Catalysts
carbene

Keywords

  • Alcoholic solution
  • Anchored Ru complex
  • Aqueous solution
  • Hydrogenations

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

New application of an anchored Ru(II)-N-heterocyclic carbene complex. / Zsigmond, A.; Undrala, Sushen; Notheisz, F.; Papp, Gábor; Joó, Ferenc.

In: Catalysis Letters, Vol. 115, No. 3-4, 06.2007, p. 163-168.

Research output: Contribution to journalArticle

Zsigmond, A. ; Undrala, Sushen ; Notheisz, F. ; Papp, Gábor ; Joó, Ferenc. / New application of an anchored Ru(II)-N-heterocyclic carbene complex. In: Catalysis Letters. 2007 ; Vol. 115, No. 3-4. pp. 163-168.
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