Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid

Gerjgely Kali, Theoni K. Georgiou, B. Iván, Costas S. Patrickios, Elena Loizou, Yi Thomann, Joerg Tiller

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Two series of model amphiphilic polymer conetworks were synthesized by group transfer polymerization (GTP). The first one contained methyl methacrylate (MMA) and the second one 2-butyl-l-octyl methacrylate (BOMA) as hydrophobic monomers. Methacrylic acid (MAA) was used as the hydrophilic monomer for both series. Network synthesis was performed by sequential monomer/cross-linker additions to form conetworks in a wide range of compositions and architectures. All conetwork precursors and the extractables were characterized in organic solvents by gel permeation chromatography and 1H NMR. The polymer conetworks were investigated in terms of their degree of swelling in aqueous media and in THF. The nanophase separated structure was proved by atomic force microscopy and small-angle neutron scattering measurements for the triblock copolymer model conetworks.

Original languageEnglish
Title of host publication2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings
Pages60-63
Number of pages4
Volume2
Publication statusPublished - 2007
Event2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007 - Santa Clara, CA, United States
Duration: May 20 2007May 24 2007

Other

Other2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007
CountryUnited States
CitySanta Clara, CA
Period5/20/075/24/07

Fingerprint

Monomers
Acids
Gel permeation chromatography
Polymers
Neutron scattering
Organic solvents
Block copolymers
Swelling
Atomic force microscopy
Polymerization
Nuclear magnetic resonance
Chemical analysis

Keywords

  • AFM
  • Amphiphilic conetworks
  • GTP
  • Nanophases
  • SANS

ASJC Scopus subject areas

  • Mechanical Engineering

Cite this

Kali, G., Georgiou, T. K., Iván, B., Patrickios, C. S., Loizou, E., Thomann, Y., & Tiller, J. (2007). Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid. In 2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings (Vol. 2, pp. 60-63)

Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid. / Kali, Gerjgely; Georgiou, Theoni K.; Iván, B.; Patrickios, Costas S.; Loizou, Elena; Thomann, Yi; Tiller, Joerg.

2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings. Vol. 2 2007. p. 60-63.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Kali, G, Georgiou, TK, Iván, B, Patrickios, CS, Loizou, E, Thomann, Y & Tiller, J 2007, Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid. in 2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings. vol. 2, pp. 60-63, 2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Santa Clara, CA, United States, 5/20/07.
Kali G, Georgiou TK, Iván B, Patrickios CS, Loizou E, Thomann Y et al. Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid. In 2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings. Vol. 2. 2007. p. 60-63
Kali, Gerjgely ; Georgiou, Theoni K. ; Iván, B. ; Patrickios, Costas S. ; Loizou, Elena ; Thomann, Yi ; Tiller, Joerg. / Nanophase separated anionic amphiphilic model conetworks based on methacrylic acid. 2007 NSTI Nanotechnology Conference and Trade Show - NSTI Nanotech 2007, Technical Proceedings. Vol. 2 2007. pp. 60-63
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