Multinuclear and 2D NMR structural study of methyl-substituted 1,3-dioxadecalanes

Jorma Mattinen, Kalevi Pihlaja, Jószef Czombos, Mihaly Bártok

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The configurations and conformations of 11 1,3-dioxadecalane derivatives were determined by multinuclear and 2D NMR spectroscopy. No conformational equilibria were found even in the 2,2-dimethyl substituted compound. In one case (9) only the O-out conformation prevails. The values of the methyl substituent effects on the 13C NMR chemical shifts of 1,3-dioxane were found useful in the present case, too. The 17O NMR chemical shifts were also helpful in both conformational and configurational assignments.

Original languageEnglish
Pages (from-to)2761-2767
Number of pages7
JournalTetrahedron
Volume43
Issue number12
DOIs
Publication statusPublished - 1987

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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