Mo5+-H and W5+-H centres in ZnWO4 single crystals characterized by ESR and ENDOR spectroscopy

A. Watterich, A. Hofstaetter, R. Wuerz, A. Scharmann, O. R. Gilliam

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

ESR and ENDOR methods are used to characterize a new Mo5+-H centre with C1 symmetry in reduced ZnWO4:Mo single crystals. Present ENDOR results also confirm that for the recently reported W5+-H centre in UV- or γ-irradiated ZnWO4:Li crystal an observed superhyperfine interaction results from a nearby hydrogen nucleus. Comparison of spin-Hamiltonian parameters shows the similarity of Mo5+-H and W5+-H centres in ZnWO4 crystals.

Original languageEnglish
Pages (from-to)205-213
Number of pages9
JournalJournal of Physics Condensed Matter
Volume10
Issue number1
DOIs
Publication statusPublished - Jan 12 1998

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

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