Molecular structure of germanium dibromide: A reinvestigation

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The electron diffraction intensities of germanium dibromide [1] were reanalyzed based on computational evidence on the geometry of the excited state molecule. It was found that beside the ground state germanium dibromide molecule a small amount of iron dibromide, rather than other germanium dibromide species, may have been present in the vapor. The revised geometrical parameters of GeBr2 are: r(g)(Ge - Br) = 2.359 ± 0.005 Å and <(a)Br - Ge - Br = 101.0 ± 0.3 Å.

Original languageEnglish
Pages (from-to)161-166
Number of pages6
JournalStructural Chemistry
Volume11
Issue number2-3
DOIs
Publication statusPublished - Jan 1 2000

    Fingerprint

Keywords

  • Ab initio calculation
  • Electron diffraction
  • GeBr
  • Germanium dibromide
  • Molecular structure

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Cite this