Molecular structure of allyl radical from electron diffraction

E. Vajda, J. Tremmel, B. Rozsondai, I. Hargittai, A. K. Maltsev, N. D. Kagramanov, O. M. Nefedov

Research output: Contribution to journalArticle

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Abstract

The molecular structure of free allyl radical was determined from high-temperature electron diffraction augmented with mass spectrometry. The free radicals, with 75% relative abundance, were produced by vacuum pyrolysis of 1,5-hexadiene at 960°C in the diffraction experiment. The data are consistent with a planar symmetric geometry, C-C bond length (rg) 1.428 ± 0.013 Å, and C-C-C bond angle 124.6 ± 3.4°.

Original languageEnglish
Pages (from-to)4352-4353
Number of pages2
JournalJournal of the American Chemical Society
Volume108
Issue number15
Publication statusPublished - 1986

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Bond length
Molecular Structure
Free radicals
Electron diffraction
Molecular structure
Free Radicals
Mass spectrometry
Pyrolysis
Diffraction
Vacuum
Electrons
Geometry
Mass Spectrometry
Experiments
Temperature
1,5-hexadiene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Vajda, E., Tremmel, J., Rozsondai, B., Hargittai, I., Maltsev, A. K., Kagramanov, N. D., & Nefedov, O. M. (1986). Molecular structure of allyl radical from electron diffraction. Journal of the American Chemical Society, 108(15), 4352-4353.

Molecular structure of allyl radical from electron diffraction. / Vajda, E.; Tremmel, J.; Rozsondai, B.; Hargittai, I.; Maltsev, A. K.; Kagramanov, N. D.; Nefedov, O. M.

In: Journal of the American Chemical Society, Vol. 108, No. 15, 1986, p. 4352-4353.

Research output: Contribution to journalArticle

Vajda, E, Tremmel, J, Rozsondai, B, Hargittai, I, Maltsev, AK, Kagramanov, ND & Nefedov, OM 1986, 'Molecular structure of allyl radical from electron diffraction', Journal of the American Chemical Society, vol. 108, no. 15, pp. 4352-4353.
Vajda E, Tremmel J, Rozsondai B, Hargittai I, Maltsev AK, Kagramanov ND et al. Molecular structure of allyl radical from electron diffraction. Journal of the American Chemical Society. 1986;108(15):4352-4353.
Vajda, E. ; Tremmel, J. ; Rozsondai, B. ; Hargittai, I. ; Maltsev, A. K. ; Kagramanov, N. D. ; Nefedov, O. M. / Molecular structure of allyl radical from electron diffraction. In: Journal of the American Chemical Society. 1986 ; Vol. 108, No. 15. pp. 4352-4353.
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