Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones

Ádám Gyömöre, Mária Bakos, Tamás Földes, I. Pápai, Attila Domján, T. Soós

Research output: Contribution to journalArticle

70 Citations (Scopus)

Abstract

In this paper, we report on the development of a bench-stable borane for frustrated Lewis pair catalyzed reduction of aldehydes, ketones, and enones. The deliberate fine-tuning of structural and electronic parameters of Lewis acid component and the choice of Lewis base provided for the first time, a moisture-tolerant FLP catalyst. Related NMR and DFT studies underpinned the unique behavior of this FLP catalyst and gave insight into the catalytic activity of the resulting FLP catalyst.

Original languageEnglish
Pages (from-to)5366-5372
Number of pages7
JournalACS Catalysis
Volume5
Issue number9
DOIs
Publication statusPublished - Jul 31 2015

Fingerprint

Ketones
Aldehydes
Hydrogenation
Moisture
Catalysts
Lewis Bases
Boranes
Lewis Acids
Discrete Fourier transforms
Catalyst activity
Tuning
Nuclear magnetic resonance
Acids

Keywords

  • carbonyl
  • catalysis
  • frustrated Lewis pair
  • hydrogenation
  • moisture tolerant

ASJC Scopus subject areas

  • Catalysis

Cite this

Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones. / Gyömöre, Ádám; Bakos, Mária; Földes, Tamás; Pápai, I.; Domján, Attila; Soós, T.

In: ACS Catalysis, Vol. 5, No. 9, 31.07.2015, p. 5366-5372.

Research output: Contribution to journalArticle

Gyömöre, Ádám ; Bakos, Mária ; Földes, Tamás ; Pápai, I. ; Domján, Attila ; Soós, T. / Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones. In: ACS Catalysis. 2015 ; Vol. 5, No. 9. pp. 5366-5372.
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