Modification of Ni/Al203 hydrogenation catalysts with lead by using Controlled Surface Reactions

J. L. Margitfalvi, S. Gobölös, M. Hegedűs, E. Talas

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

In the present work alumina supported nickel catalysts modified oy lead were used for the selective hydrogenation of acrylonitrile to propionitrile. The unmodified nickel catalyst was not selective in this reaction. The modification of the Ni/Al203 catalyst, i.e. the preparation of Pb-Ni/A1203 catalysts was carried out by using Controlled Surface Reactions (CSRs). CSRs applied in this work are based on the reactivity of hydrogen adsorbed on the nickel. This hydrogen reacts selectively with tetraethyl lead resulting in bimetallic surface entities. Experimental results obtained both in the surface reactions Involved in the modification of the catalyst and in the study of selective hydrogenation of acrylonitrile strongly indicate that catalyst modification via CSRs is a powerful tool to design selective hydrogenation catalysts.

Original languageEnglish
Pages (from-to)145-152
Number of pages8
JournalStudies in Surface Science and Catalysis
Volume41
Issue numberC
DOIs
Publication statusPublished - 1988

Fingerprint

Surface reactions
surface reactions
Hydrogenation
hydrogenation
Lead
catalysts
Catalysts
Nickel
Acrylonitrile
acrylonitriles
nickel
Hydrogen
Tetraethyl Lead
Aluminum Oxide
hydrogen
Alumina
reactivity
aluminum oxides
preparation

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Catalysis
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Modification of Ni/Al203 hydrogenation catalysts with lead by using Controlled Surface Reactions. / Margitfalvi, J. L.; Gobölös, S.; Hegedűs, M.; Talas, E.

In: Studies in Surface Science and Catalysis, Vol. 41, No. C, 1988, p. 145-152.

Research output: Contribution to journalArticle

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