Modelling of angular dependence of superexchange: application to copper(II) dimers

M. Atanasov, S. Angelov, I. Mayer

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A model which accounts for both the kinetic and potential superexchange in σ bonded transition metal complexes is described. The relative contributions of ferromagnetic and antiferromagnetic interactions to the total exchange constant are discussed. The model is applied in a parametrical form to correlate experimental magnetochemical data on mono- and bi-hydroxo-bridged copper(II) dimers with their bridging geometry.

Original languageEnglish
Pages (from-to)23-33
Number of pages11
JournalJournal of Molecular Structure: THEOCHEM
Volume187
Issue numberC
DOIs
Publication statusPublished - May 1989

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ASJC Scopus subject areas

  • Biochemistry
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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