Modelling of angular dependence of superexchange

application to copper(II) dimers

M. Atanasov, S. Angelov, I. Mayer

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A model which accounts for both the kinetic and potential superexchange in σ bonded transition metal complexes is described. The relative contributions of ferromagnetic and antiferromagnetic interactions to the total exchange constant are discussed. The model is applied in a parametrical form to correlate experimental magnetochemical data on mono- and bi-hydroxo-bridged copper(II) dimers with their bridging geometry.

Original languageEnglish
Pages (from-to)23-33
Number of pages11
JournalJournal of Molecular Structure: THEOCHEM
Volume187
Issue numberC
DOIs
Publication statusPublished - 1989

Fingerprint

Coordination Complexes
Dimers
Copper
dimers
copper
Metal complexes
Transition metals
transition metals
Kinetics
Geometry
kinetics
geometry
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Computational Theory and Mathematics
  • Atomic and Molecular Physics, and Optics

Cite this

Modelling of angular dependence of superexchange : application to copper(II) dimers. / Atanasov, M.; Angelov, S.; Mayer, I.

In: Journal of Molecular Structure: THEOCHEM, Vol. 187, No. C, 1989, p. 23-33.

Research output: Contribution to journalArticle

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