Mild Palladium Catalyzed ortho C-H Bond Functionalizations of Aniline Derivatives

Ms Orsolya Tischler, Mr Balázs Tóth, Z. Novák

Research output: Contribution to journalReview article

13 Citations (Scopus)

Abstract

This account collects the developments and transformations which avoid the utilization of harsh reaction conditions in the field of palladium catalyzed, ortho-directed C−H activation of aniline derivatives from the first attempts to up-to-date results, including the results of our research laboratory. The discussed functionalizations performed under mild conditions include acylation, olefination, arylation, alkylation, alkoxylation reactions. Beside the optimization studies and the synthetic applications mechanistic investigations are also presented.

Original languageEnglish
Pages (from-to)184-199
Number of pages16
JournalChemical Record
Volume17
Issue number2
DOIs
Publication statusPublished - Feb 1 2017

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Keywords

  • Acetanilide
  • C−H activation
  • mild transformations
  • palladium
  • urea

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry
  • Chemical Engineering(all)
  • Biochemistry, medical
  • Materials Chemistry

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