Migration-driven instability in the chlorite-tetrathionate reaction

Zsanett Virányi, Dezsó Horváth, Ágota Tóth

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10 Citations (Scopus)

Abstract

We have studied the lateral stability of planar reaction-diffusion fronts in an autocatalytic reaction between aqueous ions in an externally imposed electric field. In our experiments, migration drives the pattern formation leading to cellular structures where the sufficiently greater migrational flux of the reactant with respect to that of the autocatalyst is the driving force. The difference in electric field strength between the two sides of the thin reaction front results from the significant increase in conductivity during the reaction. The results of the theoretical analysis based on the empirical rate-law model of the reaction reproduce the behavior observed experimentally.

Original languageEnglish
Pages (from-to)3614-3618
Number of pages5
JournalJournal of Physical Chemistry A
Volume110
Issue number10
DOIs
Publication statusPublished - Mar 16 2006

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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