Microwave-assisted alcoholysis of dialkyl H-phosphonates by diols and amino alcohols

Ádám Tajti, G. Keglevich, Erika Bálint

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4 Citations (Scopus)

Abstract

The microwave-assisted alcoholysis of dialkyl H-phosphonates with diols and amino alcohols aiming at P-functionalized monomers was studied. Depending on the conditions (molar ratio, temperature, time), the reaction could be fine-tuned to afford the target mono and bis hydroxyalkyl or aminoalkyl H-phopshonate derivatives. The formation of three types of by-products was also investigated. Thermal accomplishments showed lower efficiency in the transesterifications.

Original languageEnglish
Pages (from-to)769-775
Number of pages7
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume192
Issue number6
DOIs
Publication statusPublished - Jun 3 2017

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Keywords

  • Alcoholysis
  • bifunctional nucleophiles
  • H-phosphonate monomers
  • microwave
  • optimization

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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