Mechanism of the oscillatory decomposition of the dithionite ion in a flow reactor

Klára M. Kovács, G. Rábai

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A simple mechanism consisting of three protonation equilibria and seven redox reactions between sulfur species can describe the large amplitude-sustained temporal pH-oscillations observed during acid-induced decomposition of the dithionite ion in a continuous-flow stirred tank reactor (CSTR) in the temperature range 25-60°C.

Original languageEnglish
Pages (from-to)790-791
Number of pages2
JournalChemical Communications
Issue number7
Publication statusPublished - Apr 7 2002

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Dithionite
Redox reactions
Protonation
Sulfur
Ions
Decomposition
Acids
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Mechanism of the oscillatory decomposition of the dithionite ion in a flow reactor. / Kovács, Klára M.; Rábai, G.

In: Chemical Communications, No. 7, 07.04.2002, p. 790-791.

Research output: Contribution to journalArticle

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