Mass spectrometry of very large saturated hydrocarbons

Krisztina Ludányi, Andrés Dallos, Zsolt Kühn, Károly Vékey

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Mass spectra of very large branched hydrocarbons containing up to 103 carbon atoms were studied. New and characteristic fragmentations at branching sites were identified. Medium-energy (~ 20 eV) electron ionization mass spectra were found to be most useful for structural characterization, tandem mass spectra giving important additional information. The significance of these studies is that other techniques for structure elucidation (e.g. NMR) have limited utility for this class of compounds.

Original languageEnglish
Pages (from-to)264-267
Number of pages4
JournalJournal of Mass Spectrometry
Volume34
Issue number4
DOIs
Publication statusPublished - Jan 1 1999

Keywords

  • Alkane
  • Branching position
  • Mass spectrometry
  • Mass-analysed ion kinetic energy
  • Structure elucidation

ASJC Scopus subject areas

  • Spectroscopy

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