Mass spectrometric evidences for the formation of unstable 1,1,3,3-tetramethyl-1,3-cyclodisiloxane in the gas phase

J. Tamás, A. Gömöry, I. Besenyei, O. M. Nefedov, V. N. Khabashesku, Z. A. Kerzina, N. D. Kagramanov, A. K. Maltsev

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Mass spectrometry during the vacuum pyrolysis of either 3,3-dimethyl-6-oxa-3-silabicyclo[3.1.0]hexane (1) or its 1,5-dimethyl derivative (2), both of which are dimethyl silanone (D1) precursors, indicated that 1,1,3,3-tetramethyl-1,3-cyclodi-siloxane (D2) was present among the pyrolysis products in the gas phase. D2 is unstable under normal conditions.

Original languageEnglish
Pages (from-to)37-41
Number of pages5
JournalJournal of Organometallic Chemistry
Volume349
Issue number1-2
DOIs
Publication statusPublished - Jul 19 1988

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Siloxanes
Hexanes
Vacuum
pyrolysis
Mass Spectrometry
Pyrolysis
Gases
vapor phases
siloxanes
Hexane
Mass spectrometry
mass spectroscopy
Derivatives
vacuum
products
silanone

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Mass spectrometric evidences for the formation of unstable 1,1,3,3-tetramethyl-1,3-cyclodisiloxane in the gas phase. / Tamás, J.; Gömöry, A.; Besenyei, I.; Nefedov, O. M.; Khabashesku, V. N.; Kerzina, Z. A.; Kagramanov, N. D.; Maltsev, A. K.

In: Journal of Organometallic Chemistry, Vol. 349, No. 1-2, 19.07.1988, p. 37-41.

Research output: Contribution to journalArticle

Tamás, J, Gömöry, A, Besenyei, I, Nefedov, OM, Khabashesku, VN, Kerzina, ZA, Kagramanov, ND & Maltsev, AK 1988, 'Mass spectrometric evidences for the formation of unstable 1,1,3,3-tetramethyl-1,3-cyclodisiloxane in the gas phase', Journal of Organometallic Chemistry, vol. 349, no. 1-2, pp. 37-41. https://doi.org/10.1016/0022-328X(88)80435-2
Tamás, J. ; Gömöry, A. ; Besenyei, I. ; Nefedov, O. M. ; Khabashesku, V. N. ; Kerzina, Z. A. ; Kagramanov, N. D. ; Maltsev, A. K. / Mass spectrometric evidences for the formation of unstable 1,1,3,3-tetramethyl-1,3-cyclodisiloxane in the gas phase. In: Journal of Organometallic Chemistry. 1988 ; Vol. 349, No. 1-2. pp. 37-41.
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AU - Besenyei, I.

AU - Nefedov, O. M.

AU - Khabashesku, V. N.

AU - Kerzina, Z. A.

AU - Kagramanov, N. D.

AU - Maltsev, A. K.

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