Magnetoelasticity in ACr2O4 spinel oxides (A= Mn, Fe, Co, Ni, and Cu)

V. Kocsis, S. Bordács, D. Varjas, K. Penc, A. Abouelsayed, C. A. Kuntscher, K. Ohgushi, Y. Tokura, I. Kézsmárki

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59 Citations (Scopus)

Abstract

Dynamical properties of the lattice structure were studied by optical spectroscopy in ACr2O4 chromium spinel oxide magnetic semiconductors over a broad temperature region of T=10-335 K. The systematic change of the A-site ions (A= Mn, Fe, Co, Ni and Cu) showed that the occupancy of 3d orbitals on the A site has strong impact on the lattice dynamics. For compounds with orbital degeneracy (FeCr2O4, NiCr 2O4, and CuCr2O4), clear splitting of infrared-active phonon modes and/or activation of silent vibrational modes have been observed upon the Jahn-Teller transition and at the onset of the subsequent long-range magnetic order. Although MnCr2O4 and CoCr2O4 show multiferroic and magnetoelectric character, no considerable magnetoelasticity was found in spinel compounds without orbital degeneracy as they closely preserve the high-temperature cubic spinel structure even in their magnetic ground state. Aside from lattice vibrations, intra-atomic 3d-3d transitions of the A2+ ions were also investigated to determine the crystal field and Racah parameters and the strength of the spin-orbit coupling.

Original languageEnglish
Article number064416
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume87
Issue number6
DOIs
Publication statusPublished - Feb 20 2013

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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