Magnetic properties of TM3[Cr(CN)6]2 · nH2O

M. Zentková, M. Mihalik, J. Kováč, A. Zentko, Z. Mitróová, M. Lukáčová, V. Kavečanský, L. F. Kiss

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Abstract

Magnetization measurements performed on Prussian blue analogs TM 32+ [CrIIICN)6]2 · nH2O (TM = Cr, Mn, Fe, Co, Ni, Cu) confirmed the dual character of the exchange interaction (antiferromagnetic AFM and ferromagnetic FM) in this system. AFM interaction dominates for the Cr2+ sample and with rising atomic number Z the FM interaction becomes more important reaching pure FM character for the Cu2+ sample.

Original languageEnglish
Pages (from-to)272-276
Number of pages5
JournalPhysica Status Solidi (B) Basic Research
Volume243
Issue number1
DOIs
Publication statusPublished - Jan 1 2006

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Zentková, M., Mihalik, M., Kováč, J., Zentko, A., Mitróová, Z., Lukáčová, M., Kavečanský, V., & Kiss, L. F. (2006). Magnetic properties of TM3[Cr(CN)6]2 · nH2O. Physica Status Solidi (B) Basic Research, 243(1), 272-276. https://doi.org/10.1002/pssb.200562463