Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules

P. Rakyta, A. Alanazy, A. Kormányos, Z. Tajkov, G. Kukucska, J. Koltai, S. Sangtarash, H. Sadeghi, J. Cserti, C. J. Lambert

Research output: Contribution to journalArticle

Abstract

When a single molecule is connected to external electrodes by linker groups, the connectivity of the linkers to the molecular core can be controlled to atomic precision by appropriate chemical synthesis. Recently, the connectivity dependence of the electrical conductance and Seebeck coefficient of single molecules has been investigated both theoretically and experimentally. Here, we study the connectivity dependence of the Wigner delay time of single-molecule junctions and connectivity dependence of superconducting proximity effects, which occur when the external electrodes are replaced by superconductors. Although absolute values of transport properties depend on complex and often uncontrolled details of the coupling between the molecule and electrodes, we demonstrate that ratios of transport properties can be predicted using tables of "magic numbers," which capture the connectivity dependence of superconducting proximity effects and Wigner delay times within molecules. These numbers are calculated easily, without the need for large-scale computations. For normal-molecule-superconducting junctions, we find that the electrical conductance is proportional to the fourth power of their magic numbers, whereas for superconducting-molecule-superconducting junctions, the critical current is proportional to the square of their magic numbers. For more conventional normal-molecule-normal junctions, we demonstrate that delay time ratios can be obtained from products of magic number tables.

Original languageEnglish
Pages (from-to)6812-6822
Number of pages11
JournalJournal of Physical Chemistry C
Volume123
Issue number11
DOIs
Publication statusPublished - Mar 21 2019

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number theory
Number theory
Graphite
Graphene
Time delay
graphene
time lag
Molecules
molecules
Transport properties
Electrodes
electrodes
transport properties
Seebeck coefficient
Critical currents
Seebeck effect
Superconducting materials
critical current

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Rakyta, P., Alanazy, A., Kormányos, A., Tajkov, Z., Kukucska, G., Koltai, J., ... Lambert, C. J. (2019). Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules. Journal of Physical Chemistry C, 123(11), 6812-6822. https://doi.org/10.1021/acs.jpcc.8b11161

Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules. / Rakyta, P.; Alanazy, A.; Kormányos, A.; Tajkov, Z.; Kukucska, G.; Koltai, J.; Sangtarash, S.; Sadeghi, H.; Cserti, J.; Lambert, C. J.

In: Journal of Physical Chemistry C, Vol. 123, No. 11, 21.03.2019, p. 6812-6822.

Research output: Contribution to journalArticle

Rakyta, P, Alanazy, A, Kormányos, A, Tajkov, Z, Kukucska, G, Koltai, J, Sangtarash, S, Sadeghi, H, Cserti, J & Lambert, CJ 2019, 'Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules', Journal of Physical Chemistry C, vol. 123, no. 11, pp. 6812-6822. https://doi.org/10.1021/acs.jpcc.8b11161
Rakyta, P. ; Alanazy, A. ; Kormányos, A. ; Tajkov, Z. ; Kukucska, G. ; Koltai, J. ; Sangtarash, S. ; Sadeghi, H. ; Cserti, J. ; Lambert, C. J. / Magic Number Theory of Superconducting Proximity Effects and Wigner Delay Times in Graphene-Like Molecules. In: Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 11. pp. 6812-6822.
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