Mössbauer study of phase separation in Ni8057Fe1P19 amorphous alloys

E. Kuzmann, A. Cserei, A. Vértes, I. A. Novochatskii, I. A. Usatyuk, Gy Láng, L. Kiss, F. Hajdu, L. Pöppl

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Mössbauer spectroscopy, X-ray diffractometry, scanning calorimetry and electrochemical measurements were used to study the crystallization process of Ni8057Fe1P19 amorphous alloys kept in melt at different temperatures before quenching. Samples were heated up to 430°C and 720°C at a rate of 20°C/min, in order to reach characteristically different stages of crystallization. Even at the same crystallization, stage the room temperature Mössbauer spectra and the X-ray differactograms were different depending on the temperature (1050°C or 1400°C) at which the samples were kept before quenching the melt. The Mössbauer spectra showed a paramagnetic component and two sextets (H=267 kOe and H=245 kOe) at 430°C while at 720°C there was only one sextet (H=267 kOe) besides the paramagnetic component. The changes in the Mössbauer spectra of different samples due to crystallization are consistent with the explanation that phase separation occurs in Ni8057Fe1P19 rapidly quenched from the melting temperature of 1050°C.

Original languageEnglish
Pages (from-to)611-614
Number of pages4
JournalHyperfine Interactions
Volume69
Issue number1-4
DOIs
Publication statusPublished - Apr 1992

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Mössbauer study of phase separation in Ni<sub>80</sub><sup>57</sup>Fe<sub>1</sub>P<sub>19</sub> amorphous alloys'. Together they form a unique fingerprint.

  • Cite this