The equilibrium constante of solvate formation in CCl4 and benzene as indifferent solvents has been determined by means of Mössbauer spectroscopy: SnX4 + 2D ⇌ SnX4D2, where X = I or Br, D is the donor solvent trimethylisopropoxysilane, (CH3)2CHOSi(CH3)3, or acetic anhydride. For the solution containing SnI4, trimethylisopropoxysilane and CCl4 K = (1.4 ± 0.3) × 102 [mol(kg of CCl4)-1]-2, and for SnBr4, acetic anhydride, and benzene K = 3.15 ± 1.05 [mol(kg of benzene)-1]-2.
|Number of pages||3|
|Journal||The Journal of Physical Chemistry|
|Publication status||Published - Dec 1 1975|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry