Mössbauer spectroscopic study of the reductive decomposition of iron(III) complexes

I. Zay, A. Vértes, G. Takácsi Nagy, M. Suba, K. Burger

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Iron injections containing high spin iron(III) complexes may undergo a reductive decomposition during preparation or storage. This process was investigated by the Mössbauer spectroscopy of ice samples prepared by quick-freezing of the injection. The comparison of three model compounds and the correlation between the osmotic pressure of the solutions and their iron(II) concentration formed in the decomposition process and determined by Mössbauer measurements revealed the reason and mechanism of the decomposition.

Original languageEnglish
Pages (from-to)343-350
Number of pages8
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume88
Issue number2
DOIs
Publication statusPublished - Feb 1985

Fingerprint

Iron
Decomposition
Injections
Osmotic Pressure
Ice
Freezing
Spectrum Analysis
Spectroscopy

ASJC Scopus subject areas

  • Nuclear Energy and Engineering
  • Inorganic Chemistry
  • Analytical Chemistry

Cite this

Mössbauer spectroscopic study of the reductive decomposition of iron(III) complexes. / Zay, I.; Vértes, A.; Nagy, G. Takácsi; Suba, M.; Burger, K.

In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 88, No. 2, 02.1985, p. 343-350.

Research output: Contribution to journalArticle

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