Mössbauer spectroscopic investigations of intra- and intermolecularly coordinated organotin compounds

K. Jurkschat, A. Tzschach, H. Weichmann, P. Rajczy, M. A. Mostafa, L. Korecz, K. Burger

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Abstract

The Mössbauer parameters are reported on twenty-five tetra-, penta- and hexacoordinated organotin compounds of the general types RSn(CH2CH2CH2)3N (R=Cl, Me), RR'Sn(CH2CH2CH2)2E (R=Cl, Me; R′=Cl, Me; E=NMe, O), Me2ClSnCH2CH2CH2E (E=NMe2, PPhBut, MeNCH2CH2N- (Me)CH2CH2CH2SnMe2Cl), RR′Sn[CH2CH2CH2N(Me)CH2]2 (R=R′=Cl, Br, I, SPh; R=Me, R′=Cl), {SSn[CH2CH2CH2N(Me)CH2]2}2, Cl2Sn(CH2CH2CH2NMe2)2, S(CH2CH2CH2SnMe3-n)Cln)2 (n = 1,2), Et(3-n)XnSnCH2CH2E (n = 0, E = P(O)(OEt)Ph, P(O)Bu2; n = 1, X = Br, E = P(O)(OEt)Ph, P(O)Bu2), Me2ClSnCH2CH2PPh2 and Ph(O)P(CH2CH2SnClMe2)2. Quadrupole splitting and η values calculated on the basis of the concept of partial quadrupole splittings are in agreement with the molecular structures concluded from X-ray measurements and NMR studies.

Original languageEnglish
Pages (from-to)83-88
Number of pages6
JournalInorganica Chimica Acta
Volume179
Issue number1
DOIs
Publication statusPublished - Jan 2 1991

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Organotin Compounds
Molecular structure
Nuclear magnetic resonance
X rays
quadrupoles
Rubiaceae
Molecular Structure
molecular structure
X-Rays
nuclear magnetic resonance
x rays

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Mössbauer spectroscopic investigations of intra- and intermolecularly coordinated organotin compounds. / Jurkschat, K.; Tzschach, A.; Weichmann, H.; Rajczy, P.; Mostafa, M. A.; Korecz, L.; Burger, K.

In: Inorganica Chimica Acta, Vol. 179, No. 1, 02.01.1991, p. 83-88.

Research output: Contribution to journalArticle

Jurkschat, K. ; Tzschach, A. ; Weichmann, H. ; Rajczy, P. ; Mostafa, M. A. ; Korecz, L. ; Burger, K. / Mössbauer spectroscopic investigations of intra- and intermolecularly coordinated organotin compounds. In: Inorganica Chimica Acta. 1991 ; Vol. 179, No. 1. pp. 83-88.
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abstract = "The M{\"o}ssbauer parameters are reported on twenty-five tetra-, penta- and hexacoordinated organotin compounds of the general types RSn(CH2CH2CH2)3N (R=Cl, Me), RR'Sn(CH2CH2CH2)2E (R=Cl, Me; R′=Cl, Me; E=NMe, O), Me2ClSnCH2CH2CH2E (E=NMe2, PPhBut, MeNCH2CH2N- (Me)CH2CH2CH2SnMe2Cl), RR′Sn[CH2CH2CH2N(Me)CH2]2 (R=R′=Cl, Br, I, SPh; R=Me, R′=Cl), {SSn[CH2CH2CH2N(Me)CH2]2}2, Cl2Sn(CH2CH2CH2NMe2)2, S(CH2CH2CH2SnMe3-n)Cln)2 (n = 1,2), Et(3-n)XnSnCH2CH2E (n = 0, E = P(O)(OEt)Ph, P(O)Bu2; n = 1, X = Br, E = P(O)(OEt)Ph, P(O)Bu2), Me2ClSnCH2CH2PPh2 and Ph(O)P(CH2CH2SnClMe2)2. Quadrupole splitting and η values calculated on the basis of the concept of partial quadrupole splittings are in agreement with the molecular structures concluded from X-ray measurements and NMR studies.",
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AU - Mostafa, M. A.

AU - Korecz, L.

AU - Burger, K.

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N2 - The Mössbauer parameters are reported on twenty-five tetra-, penta- and hexacoordinated organotin compounds of the general types RSn(CH2CH2CH2)3N (R=Cl, Me), RR'Sn(CH2CH2CH2)2E (R=Cl, Me; R′=Cl, Me; E=NMe, O), Me2ClSnCH2CH2CH2E (E=NMe2, PPhBut, MeNCH2CH2N- (Me)CH2CH2CH2SnMe2Cl), RR′Sn[CH2CH2CH2N(Me)CH2]2 (R=R′=Cl, Br, I, SPh; R=Me, R′=Cl), {SSn[CH2CH2CH2N(Me)CH2]2}2, Cl2Sn(CH2CH2CH2NMe2)2, S(CH2CH2CH2SnMe3-n)Cln)2 (n = 1,2), Et(3-n)XnSnCH2CH2E (n = 0, E = P(O)(OEt)Ph, P(O)Bu2; n = 1, X = Br, E = P(O)(OEt)Ph, P(O)Bu2), Me2ClSnCH2CH2PPh2 and Ph(O)P(CH2CH2SnClMe2)2. Quadrupole splitting and η values calculated on the basis of the concept of partial quadrupole splittings are in agreement with the molecular structures concluded from X-ray measurements and NMR studies.

AB - The Mössbauer parameters are reported on twenty-five tetra-, penta- and hexacoordinated organotin compounds of the general types RSn(CH2CH2CH2)3N (R=Cl, Me), RR'Sn(CH2CH2CH2)2E (R=Cl, Me; R′=Cl, Me; E=NMe, O), Me2ClSnCH2CH2CH2E (E=NMe2, PPhBut, MeNCH2CH2N- (Me)CH2CH2CH2SnMe2Cl), RR′Sn[CH2CH2CH2N(Me)CH2]2 (R=R′=Cl, Br, I, SPh; R=Me, R′=Cl), {SSn[CH2CH2CH2N(Me)CH2]2}2, Cl2Sn(CH2CH2CH2NMe2)2, S(CH2CH2CH2SnMe3-n)Cln)2 (n = 1,2), Et(3-n)XnSnCH2CH2E (n = 0, E = P(O)(OEt)Ph, P(O)Bu2; n = 1, X = Br, E = P(O)(OEt)Ph, P(O)Bu2), Me2ClSnCH2CH2PPh2 and Ph(O)P(CH2CH2SnClMe2)2. Quadrupole splitting and η values calculated on the basis of the concept of partial quadrupole splittings are in agreement with the molecular structures concluded from X-ray measurements and NMR studies.

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