Mössbauer and XRD study of novel quaternary Sn-Fe-Co-Ni electroplated alloy

E. Kuzmann, L. Sziráki, S. Stichleutner, Z. Homonnay, G. B. Lak, M. El-Sharif, C. U. Chisholm

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Abstract

Constant current electrochemical deposition technique was used to obtain quaternary alloys of Sn-Fe-Co-Ni from a gluconate electrolyte, which to date have not been reported in the literature. For the characterization of electroplated alloys, 57Fe and 119Sn Conversion Electron Mössbauer Spectroscopy (CEMS), XRD and SEM/EDAX were used. XRD revealed the amorphous character of the novel Sn-Fe-Co-Ni electrodeposited alloys. 57Fe Mössbauer spectrum of quaternary deposit with composition of 37.0 at% Sn, 38.8 at% Fe, 16.8 at% Co and 7.4 at% Ni displayed a magnetically split sextet (B = 28.9T) with broad lines typical of iron bearing ferromagnetic amorphous alloys. Magnetically split 119Sn spectra reflecting a transferred hyperfine field (B = 2.3T) were also observed. New quaternary Sn-Fe-Co-Ni alloys were successfully prepared.

Original languageEnglish
Article number97
JournalHyperfine Interactions
Volume238
Issue number1
DOIs
Publication statusPublished - Nov 1 2017

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Keywords

  • Fe and Sn Mössbauer spectroscopy
  • CEMS
  • Electrodeposition
  • Quaternary Sn-Fe-Co-Ni alloy
  • SEM/EDAX
  • XRD

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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