Mössbauer and NMR study of novel Tin(IV)-lactames

Erno Kuzmann, Roland Szalay, Zoltan Homonnay, Sandor Nagy

Research output: Contribution to journalArticle

Abstract

N-tributylstannylated 2-pyrrolidinone was reacted with tributyltin triflate in different molar ratios and the complex formation monitored using 1H-NMR, 13C-NMR and 119Sn Mössbauer spectroscopy. Comparing the carbon NMR and tin Mössbauer results, a reaction scheme is suggested for the complexation which assumes the formation of a simultaneously O- and N-tributylstannylated pyrrolidinone cation. The formation of the only O-stannylated pyrrolidinone is also assumed to account for the non-constant Mössbauer parameters of the two tin environments in the distannylated pyrrolidinone cation when the ratio of tributyltin triflate is increased in the reaction.

Original languageEnglish
Pages (from-to)7-11
Number of pages5
JournalHyperfine Interactions
Volume205
Issue number1-3
DOIs
Publication statusPublished - Mar 1 2012

Keywords

  • NMR
  • Sn Mössbauer spectroscopy
  • Tin(IV) lactames

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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