Levulinic acid esterification on SO3H-modified mesoporous silicas

H. I. Lazarova, M. D. Popova, A. Szegedi, B. Likozar, V. Dasireddy, N. Novak-Tusar

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Ordered mesoporous SBA-15 silica and a nanosized KIL-2 material with textural mesoporosity were synthesised and modified with sulphonic groups. Functionalisation with SO3H groups was performed by a two-step procedure, in which mercapto-modified mesoporous silicas were obtained first in reaction with mercaptosilane followed by treatment in H2O2 to result SO3H-modified mesoporous silicas. Initial and SO3H-containing mesoporous materials were char-acterised by X-ray diffraction (XRD), N2 physisorption, TG analysis, and TPD of ammonia. The catalytic performance of the SO3H/SBA-15 and SO3H/KIL-2 catalysts was studied in levulinic acid esterification with ethanol. A sulphonic-functionalised SBA-15 mesoporous material showed a higher conversion of levulinic acid to ethyl levulinate.

Original languageEnglish
Pages (from-to)56-60
Number of pages5
JournalBulgarian Chemical Communications
Volume50
Publication statusPublished - Jan 1 2018

    Fingerprint

Keywords

  • Biomass valorisation
  • KIL-2
  • Levulinic acid esterification
  • Mesoporous silicas
  • SBA-15

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Lazarova, H. I., Popova, M. D., Szegedi, A., Likozar, B., Dasireddy, V., & Novak-Tusar, N. (2018). Levulinic acid esterification on SO3H-modified mesoporous silicas. Bulgarian Chemical Communications, 50, 56-60.