Large-scale dosimetry using dilute methylene blue dye in aqueous solution

A. Kovács, L. Wojnárovits, C. Kurucz, M. Al-Sheikhly, W. L. McLaughlin

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The radiolytic bleaching of neat aerated methylene blue solutions is relatively stable, when irradiated to doses in the range of 50 to 500 Gy and measured at the main peak of absorption band of the dye (664 nm). The useful range can be extended up to about 5 kGy if the aqueous dye solution contains about 0.1% ethanol by volume and to 10 kGy with 5% ethanol. By increasing the concentration of the dye in the presence of 5% ethanol doses up to about 30 kGy can be measured. The spectrophotometric readings have to be made during a period of post irradiation stability of 24 hours, after which there is about a 10% increase in absorbance over the next three days due to regeneration of the dye by spontaneous oxidation. Since the industrial grade monovalent dye salt is very inexpensive and is relatively non-toxic, it may be used for dosimetry studies in quality control tests of electron beam processing of large volumes of waste water, when typical doses in the range of 5-30 kGy are required. The influences of dose, dose rate and solute concentration on the bleaching process have been investigated in terms of the decrease of the absorbance of the dye.

Original languageEnglish
Pages (from-to)539-542
Number of pages4
JournalRadiation Physics and Chemistry
Volume52
Issue number1-6
DOIs
Publication statusPublished - Jun 1998

Fingerprint

methylene blue
dosimeters
dyes
aqueous solutions
dosage
ethyl alcohol
bleaching
waste water
quality control
regeneration
grade
solutes
electron beams
salts
absorption spectra
oxidation
irradiation

Keywords

  • Gamma and electron irradiation
  • Ionizing radiation
  • Methylene blue dye
  • Radiation dosimetry

ASJC Scopus subject areas

  • Radiation

Cite this

Large-scale dosimetry using dilute methylene blue dye in aqueous solution. / Kovács, A.; Wojnárovits, L.; Kurucz, C.; Al-Sheikhly, M.; McLaughlin, W. L.

In: Radiation Physics and Chemistry, Vol. 52, No. 1-6, 06.1998, p. 539-542.

Research output: Contribution to journalArticle

Kovács, A. ; Wojnárovits, L. ; Kurucz, C. ; Al-Sheikhly, M. ; McLaughlin, W. L. / Large-scale dosimetry using dilute methylene blue dye in aqueous solution. In: Radiation Physics and Chemistry. 1998 ; Vol. 52, No. 1-6. pp. 539-542.
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