Kinetics of the reactions of pentacyanonitrosylferrate(II) with mono- and diamino acids

A. Kathó, Zs Bódi, L. Dózsa, M. T. Beck

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The reaction of Fe(CN)5NO2- with glycine, α-alanine, β-alanine, γ-aminobutyric acid, ornithine and lysine were gas-volumetrically studied in a weakly-alkaline medium. The kinetic data show that the reactivity of the amino group depends on the basicity of the amine, on the behaviour of nucleophilic centers of the carbon chain, and on their steric positions. The kinetic results are compared to the data of the reactions of amino acids with nitrous acid and of the complex with aliphatic amines.

Original languageEnglish
Pages (from-to)145-150
Number of pages6
JournalInorganica Chimica Acta
Volume83
Issue number3
DOIs
Publication statusPublished - Apr 2 1984

Fingerprint

alanine
Alanine
Amines
Amino acids
amines
Nitrous Acid
nitrous acid
Aminobutyrates
acids
Kinetics
Acids
Ornithine
lysine
kinetics
Alkalinity
glycine
Glycine
Lysine
amino acids
Carbon

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Kinetics of the reactions of pentacyanonitrosylferrate(II) with mono- and diamino acids. / Kathó, A.; Bódi, Zs; Dózsa, L.; Beck, M. T.

In: Inorganica Chimica Acta, Vol. 83, No. 3, 02.04.1984, p. 145-150.

Research output: Contribution to journalArticle

Kathó, A. ; Bódi, Zs ; Dózsa, L. ; Beck, M. T. / Kinetics of the reactions of pentacyanonitrosylferrate(II) with mono- and diamino acids. In: Inorganica Chimica Acta. 1984 ; Vol. 83, No. 3. pp. 145-150.
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