Kinetics of tetracobalt dodecacarbonyl formation from dicobalt octacarbonyl in heptane

F. Ungváry, L. Markó

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Abstract

The decomposition of Co2(CO)8 to Co4(CO)12 in heptane can be described by the kinetic equation: {A figure is presented} Dicobalt heptacarbonyl formed in a fast pre-equilibrium: {A figure is presented} is a possible intermediate of the reaction. The values for the equilibrium constant KD1 calculated from the kinetics of Co2(CO)8 decomposition are in good agreement with results from independent measurements.

Original languageEnglish
Pages (from-to)283-286
Number of pages4
JournalJournal of Organometallic Chemistry
Volume71
Issue number2
DOIs
Publication statusPublished - May 21 1974

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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