Kinetics of formation and decay of 4-methyl-2,6-di-t-butylphenoxyl radicals in cyclohexane solution

O. Brede, L. Wojnárovits

Research output: Contribution to journalArticle

Abstract

In a combined pulse and γ-radiolysis study it is shown that the 4-methyl-2,6-di-t-butylphenoxyl radical formed by the reaction of alkyl and alkylperoxi radicals rearranges with k=4×104s-1 to a benzyl type radical. The latter is the determining species for the generation of stable degradation products.

Original languageEnglish
Pages (from-to)537-548
Number of pages12
JournalInternational Journal of Radiation Applications and Instrumentation. Part
Volume37
Issue number3
DOIs
Publication statusPublished - 1991

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