Kinetics and mechanism of the reaction of HCo(CO)4 with ethyl acrylate. Conversion of (1-(ethoxycarbonyl)ethyl)cobalt tetracarbonyl to (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl

F. Ungváry, László Markó

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24 Citations (Scopus)

Abstract

The dicobalt octacarbonyl catalyzed reaction of hydridocobalt tetracarbonyl and ethyl acrylate in the presence of carbon monoxide results under kinetically controlled conditions (25°C) the latter complex is transformed into (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl which is the precursor of ethyl 3-formylpropionate. This temperature effect is in accordance with the known influence of temperature on the distribution of isomeric aldehydes in the catalytic hydroformylation of ethyl acrylate.

Original languageEnglish
Pages (from-to)2341-2345
Number of pages5
JournalOrganometallics
Volume5
Issue number11
Publication statusPublished - 1986

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Carbon Monoxide
acrylates
Cobalt
cobalt
Hydroformylation
Kinetics
kinetics
aldehydes
Aldehydes
Thermal effects
carbon monoxide
temperature effects
Temperature
temperature
ethyl acrylate
dicobalt octacarbonyl

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

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abstract = "The dicobalt octacarbonyl catalyzed reaction of hydridocobalt tetracarbonyl and ethyl acrylate in the presence of carbon monoxide results under kinetically controlled conditions (25°C) the latter complex is transformed into (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl which is the precursor of ethyl 3-formylpropionate. This temperature effect is in accordance with the known influence of temperature on the distribution of isomeric aldehydes in the catalytic hydroformylation of ethyl acrylate.",
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T1 - Kinetics and mechanism of the reaction of HCo(CO)4 with ethyl acrylate. Conversion of (1-(ethoxycarbonyl)ethyl)cobalt tetracarbonyl to (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl

AU - Ungváry, F.

AU - Markó, László

PY - 1986

Y1 - 1986

N2 - The dicobalt octacarbonyl catalyzed reaction of hydridocobalt tetracarbonyl and ethyl acrylate in the presence of carbon monoxide results under kinetically controlled conditions (25°C) the latter complex is transformed into (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl which is the precursor of ethyl 3-formylpropionate. This temperature effect is in accordance with the known influence of temperature on the distribution of isomeric aldehydes in the catalytic hydroformylation of ethyl acrylate.

AB - The dicobalt octacarbonyl catalyzed reaction of hydridocobalt tetracarbonyl and ethyl acrylate in the presence of carbon monoxide results under kinetically controlled conditions (25°C) the latter complex is transformed into (3-(ethoxycarbonyl)propionyl)cobalt tetracarbonyl which is the precursor of ethyl 3-formylpropionate. This temperature effect is in accordance with the known influence of temperature on the distribution of isomeric aldehydes in the catalytic hydroformylation of ethyl acrylate.

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