Kinetics and mechanism of the decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen

F. Ungváry, L. Markó

Research output: Contribution to journalArticle

65 Citations (Scopus)

Abstract

The decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen in n-heptane follows the kinetic equation {A figure is presented} The rate determining step is a reaction between HCo(CO)3 and HCo(CO)4, which does not involve the cobalt-hydrogen bonds. The concentration of HCo(CO)3 in equilibrium with HCo(CO)4 can be calculated.

Original languageEnglish
Pages (from-to)205-209
Number of pages5
JournalJournal of Organometallic Chemistry
Volume20
Issue number1
Publication statusPublished - Nov 1969

Fingerprint

Carbon Monoxide
Cobalt
Hydrides
hydrides
Hydrogen
cobalt
Decomposition
decomposition
Kinetics
kinetics
Heptane
hydrogen
heptanes
kinetic equations
Hydrogen bonds
hydrogen bonds
dicobalt octacarbonyl

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science (miscellaneous)
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Chemical Engineering (miscellaneous)
  • Biochemistry

Cite this

Kinetics and mechanism of the decomposition of cobalt tetracarbonyl hydride to dicobalt octacarbonyl and hydrogen. / Ungváry, F.; Markó, L.

In: Journal of Organometallic Chemistry, Vol. 20, No. 1, 11.1969, p. 205-209.

Research output: Contribution to journalArticle

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