Kinetic study of the reaction of CH3O with Br and Br2

István Szilágyi, Krisztina Imrik, Dariusz Sarzińsky, Sándor Dóbé, Tibor Bérces

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The title reactions have been studied at room temperature by applying the discharge flow method coupled with laser induced fluorescence detection of methoxy radicals and resonance fluorescence detection of bromine atoms. The following rate constants were determined: CH3O + Br → products (1) k1 (298 K) = (3.4 ± 0.4 (1σ)) × 1013 cm3 mol-1 s-1, CH3O + Br2 → products (2) k2 (298 K) ≤ 5 × 108 cm3 mol-1 s-1.

Original languageEnglish
Pages (from-to)341-345
Number of pages5
JournalReaction Kinetics and Catalysis Letters
Volume77
Issue number2
DOIs
Publication statusPublished - Jan 1 2002

    Fingerprint

Keywords

  • Br atom
  • CHO radical
  • Radical-radical reactions

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this