Kinetic model of parallel self-poisoning in the catalytic hydrogenolysis of ethane on single-type surface sites

Janos Szamosi, Sandor Kristyan

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2 Citations (Scopus)

Abstract

A kinetic model for parallel competitive self-poisoning in the catalytic hydrogenolysis of ethane has been developed. It is assumed that molecular hydrogen is the bond-splitting agent in the rate-determining step, and self-poisoning itself is reversible. In addition, all active surface sites are taken to be of the same kind. The model provides a satisfactory account of the experimentally observed kinetic behavior.

Original languageEnglish
Pages (from-to)772-778
Number of pages7
JournalCanadian Journal of Chemical Engineering
Volume69
Issue number3
Publication statusPublished - Jun 1991

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Hydrogenolysis
Ethane
Kinetics
Hydrogen

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

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abstract = "A kinetic model for parallel competitive self-poisoning in the catalytic hydrogenolysis of ethane has been developed. It is assumed that molecular hydrogen is the bond-splitting agent in the rate-determining step, and self-poisoning itself is reversible. In addition, all active surface sites are taken to be of the same kind. The model provides a satisfactory account of the experimentally observed kinetic behavior.",
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