Kinetic consequences of carbocationic grafting and blocking from and onto

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Kinetic consequences of cationic grafting (or blocking) onto and from have been derived by assuming the operational presence of these two mechanisms. It has been found that high grafting (or blocking) efficiencies(f) cannot be achieved by the onto process with polymerization systems in which termination leading to homopolymer occurs. Also, f decreases with increasing monomer conversion and rapidly so near 100% conversion in grafting or blocking onto. Consequently, efficient carbocationic grafting or blocking is readily explained by grafting or blocking from rather than by grafting or blocking onto.

Original languageEnglish
Pages (from-to)365-372
Number of pages8
JournalPolymer Bulletin
Volume20
Issue number4
DOIs
Publication statusPublished - Oct 1 1988

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Polymers and Plastics
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Kinetic consequences of carbocationic grafting and blocking from and onto'. Together they form a unique fingerprint.

  • Cite this