Kinetic comparison of enantioselective hydrogenations

A. Tungle, T. Tamai, A. Deak, S. Kemény, A. Györi, T. Máthé, J. Petró

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Kinetic investigation of the Pd/carbon-(S)-proline system in reduction of isophorone and acetophenone and comparison with known enantioselective hydrogenations were camed out. An addition reaction of (S)-proline with the substrates, and the selective hydrogenation of this adduct results in the optically active products, the kinetic analysis verified this mode of action: these are rather diastereoselective reactions.

Original languageEnglish
Pages (from-to)99-106
Number of pages8
JournalStudies in Surface Science and Catalysis
Volume78
Issue numberC
DOIs
Publication statusPublished - 1993

Fingerprint

Proline
Hydrogenation
hydrogenation
Addition reactions
Kinetics
kinetics
adducts
Carbon
carbon
Substrates
products
isophorone
acetophenone

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Catalysis
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Kinetic comparison of enantioselective hydrogenations. / Tungle, A.; Tamai, T.; Deak, A.; Kemény, S.; Györi, A.; Máthé, T.; Petró, J.

In: Studies in Surface Science and Catalysis, Vol. 78, No. C, 1993, p. 99-106.

Research output: Contribution to journalArticle

Tungle, A, Tamai, T, Deak, A, Kemény, S, Györi, A, Máthé, T & Petró, J 1993, 'Kinetic comparison of enantioselective hydrogenations', Studies in Surface Science and Catalysis, vol. 78, no. C, pp. 99-106. https://doi.org/10.1016/S0167-2991(08)63308-X
Tungle, A. ; Tamai, T. ; Deak, A. ; Kemény, S. ; Györi, A. ; Máthé, T. ; Petró, J. / Kinetic comparison of enantioselective hydrogenations. In: Studies in Surface Science and Catalysis. 1993 ; Vol. 78, No. C. pp. 99-106.
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