Jet-cooled laser spectroscopy of the cyclohexoxy radical

Lily Zu, Jinjun Liu, G. Tarczay, Patrick Dupré, Terry A. Miller

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The laser-induced fluorescence and laser-exicited dispersed fluorescence spectra of the cyclohexoxy radical was observed using jet-cooled laser spectroscopy. In order to get structural information about the radical and as an aid in the conformational sorting of the spectral lines, rotationally resolved high-resolution spectra were recorded. Two different types of expansions, have demonstrated that a number of lines either nearly of entirely disappear at lowest jet temperature. It was suggested that although, five conformers of cyclohexoxy are possible, it appears that all the observed spectral bands can be accounted for by a single one.

Original languageEnglish
Pages (from-to)10579-10593
Number of pages15
JournalThe Journal of Chemical Physics
Volume120
Issue number22
DOIs
Publication statusPublished - Jun 8 2004

Fingerprint

Laser spectroscopy
laser spectroscopy
Fluorescence
Lasers
spectral bands
classifying
Sorting
laser induced fluorescence
line spectra
fluorescence
expansion
high resolution
lasers
Temperature
temperature

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Jet-cooled laser spectroscopy of the cyclohexoxy radical. / Zu, Lily; Liu, Jinjun; Tarczay, G.; Dupré, Patrick; Miller, Terry A.

In: The Journal of Chemical Physics, Vol. 120, No. 22, 08.06.2004, p. 10579-10593.

Research output: Contribution to journalArticle

Zu, Lily ; Liu, Jinjun ; Tarczay, G. ; Dupré, Patrick ; Miller, Terry A. / Jet-cooled laser spectroscopy of the cyclohexoxy radical. In: The Journal of Chemical Physics. 2004 ; Vol. 120, No. 22. pp. 10579-10593.
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