Is the adiabatic approximation sufficient to account for the post-Born-Oppenheimer effects on molecular electric dipole moments?

Sandra L. Hobson, Edward F. Valeev, Attila G. Csaszar, John F. Stanton

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

We estimated the post-Born-Oppenheimer (post-BO) contribution to electric dipole moments by finite-field derivatives of the diagonal Born-Oppenheimer correction computed with correlated electronic wave functions. The new method is used to examine the effect of isotopic substitution on the dipole moments of the HD, LiH, LiD, and H216O molecules. The non-zero dipole moment of HD is solely due to the post-BO effect and is predicted within a few percent of the best experimental and theoretical results. The post-BO contribution to the dipole moment in LiH and LiD is comparable in magnitude to that in HD, but the difference in total adiabatic dipole moments of LiH and LiD is dominated by the vibrationally averaged BO contribution, and the post-BO contribution is relatively unimportant. However, the post-BO contribution to the dipole moment in H2O is much larger than the vibrationally averaged BO contribution determined by Lodi et al. [J. Chem. Phys. 128, 044304 (2008)] and is twice as large as the discrepancy between their best theoretical BO estimate and the most recent experimental result. Our findings suggest that for species that are well behaved in the BO sense, the post-BO contribution to molecular electric dipole moments can be described within the adiabatic approximation to a few percent accuracy.

Original languageEnglish
Pages (from-to)1153-1159
Number of pages7
JournalMolecular Physics
Volume107
Issue number8-12
DOIs
Publication statusPublished - Jan 1 2009

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Keywords

  • Ab initio
  • Adiabatic approximation
  • Born-Oppenheimer approximation
  • Electronic structure
  • Molecular dipole moments

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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