Ionophores based on 1,3-dithiole-2-thione-4,5-dithiolate (DMIT) as potentiometric silver sensors

Martin R. Bryce, Brian Johnston, Ritu Kataky, Klara Toth

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A range of acyclic compounds based on 1,3-dithiole-2-thione-4,5-dithiolate (DMIT), functionalised with a silver binding chain and an alkyl chain, were synthesised and assessed as silver ionophores suitable for incorporation into potentiometric ion-selective electrodes as sensors for silver ions in photographic emulsions. The new ionophores were compared with a commercially available ionophore and a 14-crown-4-based ionophore. The membrane compositions were optimised for silver ion selectivity over a range of ions of relevance in the photographic process. 4-(Butylsulfanyl)-5-(phenylmethylthioethylsulfanyl)-1,3-dithiole-2-one was shown to be the most suitable ionophore in plasticised membrane electrodes, with a Nernstian response in the range 10-1-10-6 mol dm-3 and selectivity coefficients of the order of log K(POT)(Ag/M) ≤ -4.0.

Original languageEnglish
Pages (from-to)861-866
Number of pages6
JournalAnalyst
Volume125
Issue number5
DOIs
Publication statusPublished - Jan 1 2000

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy
  • Electrochemistry

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