Iodine chloride: A Key Intermediate in the Chlorite-Iodide Reaction

Mihály T. Beck, G. Rábai

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The enigmatic oligo-oscillatory behavior of the chlorite-iodide system, that is, the appearance of two extrema on the iodine concentration vs. time curves, can be explained by the formation and subsequent disproportionation of iodine chloride. The ratio of the iodine concentration consumed in the second phase to that regenerated in the third phase is 5:2, as required by the proposed reactions. The characteristic shape of the kinetic curves is perfectly described by considering the rate equations of four-component reactions. The partial regeneration of iodine has been observed in the chlorite-iodine reaction, too.

Original languageEnglish
Pages (from-to)2204-2205
Number of pages2
JournalJournal of Physical Chemistry
Volume90
Issue number10
Publication statusPublished - 1986

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Iodides
Iodine
iodides
iodine
chlorides
range (extremes)
curves
regeneration
Kinetics
chlorite
iodine monochloride
kinetics

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Iodine chloride : A Key Intermediate in the Chlorite-Iodide Reaction. / Beck, Mihály T.; Rábai, G.

In: Journal of Physical Chemistry, Vol. 90, No. 10, 1986, p. 2204-2205.

Research output: Contribution to journalArticle

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