Investigations on the Chemistry of Berbanes, XIII. Selective Reduction of Normal‐, Allo‐, Pseudo‐, and Epiallo‐Depyrrolo‐Yohimbone Analogues

István Tóth, Gabriella Bozsár, Lajos Szabó, József Tamás, Eszter Baitz‐Gács, Csaba Szántay

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The reduction of normal‐, allo‐, epiallo‐, and pseudo‐berbanones were studied under different conditions. Reduction with Na/alcohol always led to the thermodynamically controlled products while catalytic and NaBH4 reduction resulted almost exclusively in the kinetically controlled compounds. An interesting correlation was observed between the MS fragmentation and ring C/D stereochemistry.

Original languageEnglish
Pages (from-to)1021-1024
Number of pages4
JournalLiebigs Annalen der Chemie
Volume1987
Issue number12
DOIs
Publication statusPublished - 1987

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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