Investigation of the macromolecular stable free nitroxide radical

M. Azori, F. Tüdös, A. Rockenbauer, P. Simon

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Polystyrene containing t-butyl nitroxide groups was prepared via polymer-analogous reactions and characterized by ESR measurements. Polymerizations of MMA and styrene initiated by AIBN at 50° have been investigated in the presence of the polymeric radical samples. A definite inhibiting effect was observed without retardation of the polymerization of either monomer. A linear relationship was found between the concentration of the polymeric inhibitor and the inhibition period.

Original languageEnglish
Pages (from-to)173-176
Number of pages4
JournalEuropean Polymer Journal
Volume14
Issue number3
DOIs
Publication statusPublished - 1978

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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