Investigation of the chemical conversions of diols and organic oxides - Communication 17. Investigation of the thermal decomposition of oxacyclobutane using the microreactor technique

N. I. Shuikin, M. Bartók

Research output: Contribution to journalArticle

Abstract

1. The thermal conversion of oxacyclobutane was investigated, using a microreactor mounted in a chromatograph. 2. In the thermal decomposition of oxacyclobutane, two primary reactions take place: decomposition of oxacyclobutane, two primary reactions take place: decomposition to ethylene and formaldehyde (90%) and isomerization to propionaldehyde (10%); the latter reaction is evidently the result of the influence at the walls of the reactor. The secondary processes include decarbonylation and dehydrogenation of the primary products.

Original languageEnglish
Pages (from-to)120-122
Number of pages3
JournalBulletin of the Academy of Sciences, USSR Division of Chemical Science
Volume17
Issue number1
DOIs
Publication statusPublished - Jan 1968

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Oxides
Pyrolysis
Decomposition
Communication
Dehydrogenation
Isomerization
Formaldehyde
Hot Temperature
ethylene
propionaldehyde

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "1. The thermal conversion of oxacyclobutane was investigated, using a microreactor mounted in a chromatograph. 2. In the thermal decomposition of oxacyclobutane, two primary reactions take place: decomposition of oxacyclobutane, two primary reactions take place: decomposition to ethylene and formaldehyde (90{\%}) and isomerization to propionaldehyde (10{\%}); the latter reaction is evidently the result of the influence at the walls of the reactor. The secondary processes include decarbonylation and dehydrogenation of the primary products.",
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